منابع مشابه
Dalton Discussion 11: The renaissance of main group chemistry.
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The search for extremely sterically demanding monodentate amide ligands to access main group complexes in low-coordination numbers and highly reactive bonding modes is an area of intense research interest. The recent development of three classes of sterically demanding, monodentate amide ligands - the m-terphenyl anilides [N(R){C6H3Ar2-2,6}](-) (Ar = aryl, R = H, methyl, silyl), substituted car...
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Abnormal N-heterocyclic carbene (aNHC) adducts of zinc(II) (1) and aluminum(III) (2) were synthesized. The compounds were characterized by NMR spectroscopy and elemental analysis. The solid state structures of these complexes (1 and 2) were determined by single crystal X-ray study. Furthermore, these organozinc and organoaluminum adducts (1 and 2) were tested for the ring opening polymerization...
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In reacting flow problems involving large numbers of chemical species and reactions, reduced chemistry modeling is used to approximately describe, with fewer unknowns, the slow chemical evolutions after the rapid but brief initial transients have decayed. Diffusion transport terms, if present, are modified by the reduced chemistry approximations. This article reiterates that the use of unmodifi...
متن کاملMain group mechanochemistry
Over the past decade, mechanochemistry has emerged as a powerful methodology in the search for sustainable alternatives to conventional solvent-based synthetic routes. Mechanochemistry has already been successfully applied to the synthesis of active pharmaceutical ingredients (APIs), organic compounds, metal oxides, coordination compounds and organometallic complexes. In the main group arena, e...
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ژورنال
عنوان ژورنال: Science
سال: 2007
ISSN: 0036-8075,1095-9203
DOI: 10.1126/science.317.5843.1295b